Don’t know about Kymco since DT300 i have recently bought is my first Kymco.
But i know how Piaggio evolved from 200 to 250 cc, so maybe this info will be something you can use.
Piaggio kept exactly the same piston regarding diameter, but crankshaft was larger in circling diameter and it’s connecting rod was longer, hence the piston is traveling more. So combustion chamber grew up from 200 to 250 cc.
Unfortunately, that does not mean that you can use piston from 200 on 250 and vice versa, because intake and exhaust ports can not function properly with camshaft from other type of engine.